Season 2
Season 2 of Chuck expands the show's espionage mythology as Chuck Bartowski adjusts to his dual life, only to face immediate danger when the villainous shadow organization Fulcrum intensifies its hunt for the Intersect. The season follows Chuck's desperate quest to remove the government database from his brain so he can reclaim his normal life, a goal that appears within reach when he discovers the identity of the Intersect's brilliant creator, Orion. Amidst high-stakes missions and massive workplace chaos—such as the corporate takeover of the Buy More by the ruthless efficiency expert Emmett Milbarge—the emotional core of the season centers on the deeply agonizing, "will-they-won't-they" romance between Chuck and Sarah.
Episodes
1 Chuck Versus the First Date Sep 29, 2008 
2 Chuck Versus the Seduction Oct 6, 2008 
3 Chuck Versus the Break-Up Oct 13, 2008 
4 Chuck Versus the Cougars Oct 20, 2008 
5 Chuck Versus Tom Sawyer Oct 27, 2008 
6 Chuck Versus the Ex Nov 10, 2008 
7 Chuck Versus the Fat Lady Nov 17, 2008 
8 Chuck Versus the Gravitron Nov 24, 2008 
9 Chuck Versus the Sensei Dec 1, 2008 
10 Chuck Versus the DeLorean Dec 8, 2008 
11 Chuck Versus Santa Claus Dec 15, 2008 
12 Chuck Versus the Third Dimension Feb 2, 2009 
13 Chuck Versus the Suburbs Feb 16, 2009 
14 Chuck Versus the Best Friend Feb 23, 2009 
15 Chuck Versus the Beefcake Mar 2, 2009 
16 Chuck Versus the Lethal Weapon Mar 9, 2009 
17 Chuck Versus the Predator Mar 23, 2009 
18 Chuck Versus the Broken Heart Mar 30, 2009 
19 Chuck Versus the Dream Job Apr 6, 2009 
20 Chuck Versus the First Kill Apr 13, 2009 
21 Chuck Versus the Colonel Apr 20, 2009 
22 Chuck Versus the Ring Apr 27, 2009